Application In Synthesis of (1,10-Phenanthroline)(trifluoromethyl)copper(I). The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: (1,10-Phenanthroline)(trifluoromethyl)copper(I), is researched, Molecular C13H8CuF3N2, CAS is 1300746-79-5, about New Vistas in Transmetalation with Discrete “”AgCF3″” Species: Implications in Pd-Mediated Trifluoromethylation Reactions. Author is Martinez de Salinas, Sara; Mudarra, Angel L.; Benet-Buchholz, Jordi; Parella, Teodor; Maseras, Feliu; Perez-Temprano, Monica H..
This work describes the employment of discrete “”AgCF3″” complexes as efficient transmetalating agents to PdII to surmount overlooked challenges related to the transmetalation step in Pd-catalyzed trifluoromethylation processes. Authors report the participation of a unique silver ate (Cs)[Ag(CF3)2] complex, under stoichiometric and catalytic conditions, in the unprecedented one-pot formation of PhCF3 using PhI as starting material. Moreover, they showed that the transmetalation step, which is often ignored in these transformations, can also determine the success or failure of the coupling process.
Although many compounds look similar to this compound(1300746-79-5)Application In Synthesis of (1,10-Phenanthroline)(trifluoromethyl)copper(I), numerous studies have shown that this compound(SMILES:F[C-](F)([Cu+]1[N]2=C3C4=[N]1C=CC=C4C=CC3=CC=C2)F), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
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