Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 1300746-79-5, is researched, SMILESS is F[C-](F)([Cu+]1[N]2=C3C4=[N]1C=CC=C4C=CC3=CC=C2)F, Molecular C13H8CuF3N2Journal, Article, Beilstein Journal of Organic Chemistry called Comparative profiling of well-defined copper reagents and precursors for the trifluoromethylation of aryl iodides, Author is Kaplan, Peter T.; Lloyd, Jessica A.; Chin, Mason T.; Vicic, David A., the main research direction is aryltrifluoromethyl preparation; aryl iodide copper reagent trifluoromethylation; benchmarking; copper; fluorine; fluoroalkylation; trifluoromethylation.Name: (1,10-Phenanthroline)(trifluoromethyl)copper(I).
A number of copper reagents e.g., I were compared for their effectiveness in trifluoromethylating 4-iodobiphenyl, 4-iodotoluene, and 2-iodotoluene. Yields over time were plotted in order to refine our understanding of each reagent performance, identify any bottlenecks, and provide more insight into the rates of the reactions. Interestingly, differences in reactivity were observed when a well defined [LCuCF3] complex I was employed directly or generated in situ from precursors by published reports. Relative reactivities were also found to highly dependent on the nature of the iodoarenes.
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Reference:
Pyrazole – Wikipedia,
Pyrazoles – an overview | ScienceDirect Topics