Quality Control of 3-Hydroxy-3-phenylpropanenitrile. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 3-Hydroxy-3-phenylpropanenitrile, is researched, Molecular C9H9NO, CAS is 17190-29-3, about Alkyliron and alkylcobalt reagents. IV. Aldehyde selective cyanoalkylation with cyanoalkyl derivatives of iron(II) and other transition metals. Author is Kauffmann, Thomas; Kieper, Hans Joerg; Pieper, Hans.
The Fe reagent NCCH2FeCl is a good alternative to the known Ti reagent NCCH2Ti(OCHMe2)3 for the transfer of the cyanomethyl residue with high aldehyde vs. ketone selectivity; analogous reagents with the metals Mn, Co, Ni or Cu are unfavorable. For the aldehyde vs. ketone-selective transfer of the branched residues 1-cyanoethyl and cyanoisopropyl, the Fe reagents are distinctly better than the Ti reagents.
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Reference:
Pyrazole – Wikipedia,
Pyrazoles – an overview | ScienceDirect Topics