The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 6-Bromo-2,3-dihydrobenzo[b][1,4]dioxine, is researched, Molecular C8H7BrO2, CAS is 52287-51-1, about Mills-Nixon effect. IV. Base-catalyzed cleavage of trimethylsilylveratrole, -1,3-benzodioxole, and -1,4-benzodioxane derivatives, the main research direction is Mills Nixon effect; cleavage trimethylsilyl; veratrole trimethylsilyl cleavage; benzodioxole trimethylsilyl cleavage; benzodioxan trimethylsilyl cleavage.Product Details of 52287-51-1.
The rates of detrimethylsilylation of 3,4-(RO)2C6H3SiMe3 (I, R = Me or RR = CH2 or CH2CH2) by NaOH dissolved in H2O-Me2SO (1:9) were measured at 30°. I (RR = CH2) was more reactive than the other 2 compounds This was explained in terms of hybridization changes enforced on the ring junction carbons by the strained dioxole ring.
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Reference:
Pyrazole – Wikipedia,
Pyrazoles – an overview | ScienceDirect Topics