Formula: C9H9NO. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 3-Hydroxy-3-phenylpropanenitrile, is researched, Molecular C9H9NO, CAS is 17190-29-3, about Reactions of pentafluorophenyltrimethylsilane and cyanomethyltrimethylsilane with carbonyl compounds catalyzed by cyanide anions. Author is Gostevskii, B. A.; Kruglaya, O. A.; Albanov, A. I.; Vyazankin, N. S..
Treatment of pentafluorophenyltrimethylsilane (I) and cyanomethyltrimethylsilane (II) with enolizable ketones in the presence of a catalytic amount of potassium cyanide-18-crown-6 complex gave the corresponding trimethylsilyl enol ethers. The same dehydrogenative silylation of acetylacetone and benzoylacetone with silane I was extended to the preparation of 2,4-bis(trimethylsiloxy)-1,3-pentadiene and 1-phenyl-1,3-bis(trimethylsiloxy)-1,3-butadiene, resp. The dehydrogenative silylation of acetylacetone and benzoylacetone with dimethylbis(pentafluorophenyl)silane under the same conditions affords novel heterocycles 5-methylene-2,6-dioxa-1-silacyclohex-3-enes. In the reaction studied the silylating ability of the silanes increases in the order Me3SiCN ≃ Me2Si(CN)2 < Me3SiCH2CN < Me3SiC6F5 ≃ Me2Si(C6F5)2. Potassium cyanide-18-crown complex catalyzed the addition of silane I or II to a carbonyl group of non-enolizable compounds such as benzaldehyde, crotonaldehyde, and methyl(triethylgermyl)ketene. Compound(17190-29-3)Formula: C9H9NO received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(3-Hydroxy-3-phenylpropanenitrile), if you are interested, you can check out my other related articles.
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