The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: (1,10-Phenanthroline)(trifluoromethyl)copper(I), is researched, Molecular C13H8CuF3N2, CAS is 1300746-79-5, about Selective Synthesis of Perfluoroalkylated Corannulenes and Investigation of their Structural, Dynamic and Electrochemical Behavior, the main research direction is perfluoroalkylated corannulene selective preparation mol structure dynamic behavior electrochem; X-ray crystallography; corannulene; cyclic voltammetry; perfluoroalkylation; variable temperature NMR.Formula: C13H8CuF3N2.
Herein general methods allowing the synthesis of various perfluoroalkylated corannulenes e.g., I [R = C4F9, C6F13, C8F17] with a specific substitution pattern was reported. Variable temperature NMR spectroscopic investigations revealed dynamic behavior which was analyzed by line shape anal. The activation parameters of these dynamic processes were determined For a tetrasubstituted compound it was possible to observe through space scalar coupling. The packing motifs were elucidated by X-ray crystallog., showing that the substitution pattern as well as the size of substituents strongly influence intermol. π-stacking. The reduction potentials of the perfluoroalkylated compounds were determined by cyclic voltammetry.
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Reference:
Pyrazole – Wikipedia,
Pyrazoles – an overview | ScienceDirect Topics