An article Pd-Catalyzed Asymmetric Dearomatization of Indoles via Decarbonylative Heck-Type Reaction of Thioesters WOS:000606842300033 published article about THIOL ESTERS; FUKUYAMA REDUCTION; BOND FORMATION; PALLADIUM; EFFICIENT; CYCLIZATION; ARYLATION; ALDEHYDES; THIOETHERIFICATION; CONSTRUCTION in [Han, Ming-Liang; Xiong, Hai] Shenzhen Univ, Inst Adv Study, Coll Optoelect Engn, Shenzhen 518060, Peoples R China; [Han, Ming-Liang; Xiong, Hai] Shenzhen Univ, Key Lab Optoelect Devices & Syst, Coll Optoelect Engn, Minist Educ & Guangdong Prov, Shenzhen 518060, Peoples R China; [Huang, Wei; Liu, Yu-Wen; Liu, Min; Xu, Hui; Dai, Hui-Xiong] Chinese Acad Sci, Shanghai Inst Mat Med, Key Lab Receptor Res, Shanghai 201203, Peoples R China in 2021.0, Cited 81.0. Application In Synthesis of 3,5-Dimethyl-1H-pyrazole. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6
We report herein a palladium-catalyzed ligand-promoted asymmetric dearomatization of indoles via the decarbonylation of thioesters and the subsequent reductive Heck reaction. This protocol provides a facile and efficient way to construct an aza-quaternary stereocenter at the C2 position of indolines. A variety of functional groups and substitutions could be well tolerated, affording the substituted indolines with high enantioselectivities.
Welcome to talk about 67-51-6, If you have any questions, you can contact Han, ML; Huang, W; Liu, YW; Liu, M; Xu, H; Xiong, H; Dai, HX or send Email.. Application In Synthesis of 3,5-Dimethyl-1H-pyrazole
Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics