Name: 3,5-Dimethyl-1H-pyrazole. Recently I am researching about LATE-STAGE FUNCTIONALIZATION; DIAZO-COMPOUNDS; RH(III)-CATALYZED SYNTHESIS; BOND FUNCTIONALIZATION; DIRECT ARYLATION; CROSS-COUPLINGS; ACCESS; OLEFINATION; OXIDES; CYCLIZATION, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21772235]; CAMS Innovation Fund for Medical Sciences [2017-I2M-3-011]; Drug Innovation Major Project [2018ZX09711-001-005]; Non-profit Central Research Institute Fund of the Chinese Academy of Medical Sciences [2018PT35003, 2019-RC-HL-008]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2017M620496]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Dong, Y; Zhang, XP; Chen, JJ; Zou, WX; Lin, SW; Xu, H. The CAS is 67-51-6. Through research, I have a further understanding and discovery of 3,5-Dimethyl-1H-pyrazole
The limitations of arene C-H functionalization of aryl sulfonamides containing strongly coordinating Nheterocycles were overcome using a Rh(III) catalyst. The site-selectivity of C-H carbenoid functionalization at the ortho position relative to either the sulfonamide or N-heterocycle directing groups was elegantly switched using solvents of different polarities and different additive concentrations. Importantly, sulfonamide-group-directed ortho-C-H carbenoid functionalization tolerated strongly coordinating N-heterocycles, including pyridine, pyrrole, thiazole, pyrimidine, and pyrazine. Density functional theory (DFT) calculations were performed to rationalize the reaction mechanisms and the influence of reaction polarity.
Welcome to talk about 67-51-6, If you have any questions, you can contact Dong, Y; Zhang, XP; Chen, JJ; Zou, WX; Lin, SW; Xu, H or send Email.. Name: 3,5-Dimethyl-1H-pyrazole
Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics