Recently I am researching about ASYMMETRIC ALPHA-AMINATION; VINYLOGOUS ALDOL REACTION; ELECTROPHILIC AMINATION; HIGHLY REGIO; KETONES; ACCESS; ENALS; BONDS, Saw an article supported by the NSFCNational Natural Science Foundation of China (NSFC) [21672145, 51733007, 21906049]; Science and Technology Commission of Shanghai MunicipalityScience & Technology Commission of Shanghai Municipality (STCSM) [17JC1403700, 19JC1430100, 19JC1410301]; Drug Innovation Major Project of the Ministry of Science and Technology of China [2018ZX09711001-005-002]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Fu, X; Hao, Y; Bai, HY; Duan, AB; Zhang, SY. The CAS is 67-51-6. Through research, I have a further understanding and discovery of 3,5-Dimethyl-1H-pyrazole. Category: pyrazoles-derivatives
A cobalt-catalyzed regio- and enantioselective gamma-amination of beta,gamma-unsaturated N-acylpyrazoles that delivers the corresponding gamma-amination products in good regio- and enantioselectivity has been established. Moreover, the nitrogen-containing compounds could be easily synthesized. DFT calculations have been provided to explain regio- and enantioselectivity for this gamma-amination. The chiral gamma-amination products were readily converted into the chiral gamma-amino acid derivatives.
Category: pyrazoles-derivatives. Welcome to talk about 67-51-6, If you have any questions, you can contact Fu, X; Hao, Y; Bai, HY; Duan, AB; Zhang, SY or send Email.
Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics