An article Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction WOS:000470939200002 published article about HECK ARYLATIONS; ALLYLIC ALKYLATION; ALKALOIDS; ALKENES; CASCADE; FUNCTIONALIZATION; NUCLEOPALLADATION; HETEROCYCLES; ACTIVATION; AMIDATION in [Allen, Jamie R.; Bahamonde, Ana; Furukawa, Yukino; Sigman, Matthew S.] Univ Utah, Dept Chem, 315 S 1400 E, Salt Lake City, UT 84112 USA in 2019.0, Cited 41.0. Name: 3,5-Dimethyl-1H-pyrazole. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6
The development of an intermolecular and enantioselective aza-Wacker reaction is described. Using indoles as the N-source and a selection of alkenols as the coupling partners selective beta-hydride elimination toward the alcohol was achieved. This strategy preserves the newly formed stereocenter by preventing the formation of traditionally observed enamine products. Allylic and homoallylic alcohols with a variety of functional groups are compatible with the reaction in high enantioselectivity. Isotopic-labeling experiments support a syn aminopalladation mechanism for this new class of aza-Wacker reactions.
About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Allen, JR; Bahamonde, A; Furukawa, Y; Sigman, MS or concate me.. Name: 3,5-Dimethyl-1H-pyrazole
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Pyrazole – Wikipedia,
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