An article Intermolecular Dearomatization of Naphthalene Derivatives by Photoredox-Catalyzed 1,2-Hydroalkylation WOS:000558849500001 published article about ALPHA-AMINO-ACIDS; DIIODIDE-INDUCED CYCLIZATIONS; SAMARIUM DIIODIDE; CARBOXYLIC-ACIDS; DECARBOXYLATIVE ARYLATION; RADICAL DEAROMATIZATION; BENZENE; FUNCTIONALIZATION; STRATEGIES; SCAFFOLDS in [Cheng, Yuan-Zheng; Huang, Xu-Lun; Zhuang, Wei-Hui; Zhao, Qing-Ru; Zhang, Xiao; Mei, Tian-Sheng; You, Shu-Li] Chinese Acad Sci, Ctr Excellence Mol Synth, State Key Lab Organometall Chem, Univ Chinese Acad Sci,Shanghai Inst Organ Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China; [Zhuang, Wei-Hui; Zhang, Xiao] Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Key Lab Polymer Sci, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, 32 Shangsan Lu, Fuzhou 350007, Peoples R China in 2020.0, Cited 98.0. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6. Computed Properties of C5H8N2
An intermolecular hydroalkylative dearomatization of naphthalenes with commercially available alpha-amino acids is achieved via visible-light photoredox catalysis. With an organic photocatalyst, a series of multi-substituted 1,2-dihydronaphthalenes are obtained in good-to-excellent yields. Intriguingly, by tuning the substituents at the C2 position of naphthalenes, formal dearomative [3+2] cycloadditions occur exclusively via a hydroalkylative dearomatization-cyclization sequence. This overall redox-neutral method features mild reaction conditions, good tolerance of functionalities, and operational simplicity. Diverse downstream elaborations of the products are demonstrated. Preliminary mechanistic studies suggest the involvement of a radical-radical coupling pathway.
Computed Properties of C5H8N2. Bye, fridends, I hope you can learn more about C5H8N2, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics