Lanthanide pyrazolecarboxylates for OLEDs and bioimaging was written by Utochnikova, Valentina V.;Latipov, Egor V.;Dalinger, Alexander I.;Nelyubina, Yulia V.;Vashchenko, Andrey A.;Hoffmann, Michael;Kalyakina, Alena S.;Vatsadze, Sergey Z.;Schepers, Ute;Brase, Stefan;Kuzmina, Natalia P.. And the article was included in Journal of Luminescence in 2018.Reference of 10199-53-8 This article mentions the following:
Novel materials based on lanthanide complexes with six pyrazolecarboxylates were obtained. They possess high solubility due to the purposeful introduction of the nitrogen heteroatom in α-position to the carboxy-group, and their luminescence quantum yields reach 100%. High absorption and non-toxicity allowed their successful use for bioimaging in cellulo. While the special approach to electron transport enhancement allowed using them as OLED emission materials. In the experiment, the researchers used many compounds, for example, 1-Methyl-5-phenyl-1H-pyrazole-3-carboxylic acid (cas: 10199-53-8Reference of 10199-53-8).
1-Methyl-5-phenyl-1H-pyrazole-3-carboxylic acid (cas: 10199-53-8) belongs to pyrazole derivatives. Pyrazole has two ring nitrogen atoms in which N1 is pyrrolic and N2 is pyridine-like. The N1 nitrogen is not reactive but is deprotonated in the presence of a base-forming anion. Pyrazoles and pyrimidines have diverse biological and pharmacological activities. There are a number of antimicrobial compounds containing pyrazole moiety as the core unit. Pyrazofurin is important antimicrobial drug and 2-methylpyrimidine-4-ylamine derivatives I and II were found to be effective inhibitors of Escherichia coli PDHc-E1 with antibacterial and antifungal activity.Reference of 10199-53-8
Referemce:
Pyrazole – Wikipedia,
Pyrazoles – an overview | ScienceDirect Topics