Perkins, Robert J.’s team published research in Organic Letters in 2017-07-21 | CAS: 116228-41-2

Organic Letters published new progress about Coupling reaction catalysts (electrochem.). 116228-41-2 belongs to class pyrazoles-derivatives, name is 4-Bromo-1-tosyl-1H-pyrazole, and the molecular formula is C10H9BrN2O2S, Product Details of C10H9BrN2O2S.

Perkins, Robert J. published the artcileElectrochemical Nickel Catalysis for Sp2-Sp3 Cross-Electrophile Coupling Reactions of Unactivated Alkyl Halides, Product Details of C10H9BrN2O2S, the main research area is electrochem nickel catalysis electrophile coupling reaction alkyl halide.

A constant-current electrochem. method for reducing catalytic Ni complexes in sp2-sp3 cross-electrophile coupling reactions was developed. The electrochem. reduction provides reliable Ni catalyst activation and turnover and offers a tunable parameter for reaction optimization, in contrast to more standard activated metal powder reductants. The electrochem. reactions give yields (i.e., 51-86%) and selectivities as high or superior to those using metal powder reductants and provide access to a wider substrate scope.

Organic Letters published new progress about Coupling reaction catalysts (electrochem.). 116228-41-2 belongs to class pyrazoles-derivatives, name is 4-Bromo-1-tosyl-1H-pyrazole, and the molecular formula is C10H9BrN2O2S, Product Details of C10H9BrN2O2S.

Referemce:
Pyrazole – Wikipedia,
Pyrazoles – an overview | ScienceDirect Topics