Kumar, Rahul; Turcaud, Serge; Micouin, Laurent published the artcile< The Reaction of Dimethylalkynylaluminum Reagents with Trimethylsilyldiazomethane: Original Reactivity Leading to New α-Silylated Alkynyl Hydrazones>, Electric Literature of 13808-65-6, the main research area is methylalkynylaluminum reaction silyldiazomethane preparation silylated alkynyl hydrazone.
Trimethylsilyldiazomethane does not react as a homologating reagent but as a C-electrophilic species with dimethylalkynylaluminum reagents. This unprecedented reactivity enables a simple access to unusual α-silylated alkynyl hydrazones.
Organic Letters published new progress about Alkynes Role: RCT (Reactant), RACT (Reactant or Reagent) (aluminated). 13808-65-6 belongs to class pyrazoles-derivatives, and the molecular formula is C9H7BrN2, Electric Literature of 13808-65-6.
Referemce:
Pyrazole – Wikipedia,
Pyrazoles – an overview | ScienceDirect Topics