Tong, Chao-Lai published the artcileNucleophilic and Radical Heptafluoroisopropoxylation with Redox-Active Reagents, SDS of cas: 1289010-13-4, the publication is Angewandte Chemie, International Edition (2021), 60(42), 22915-22924, database is CAplus and MEDLINE.
The practical and efficient heptafluoroisopropoxylation reactions through the invention of a series of redox-active N-OCF(CF3)2 reagents e.g., I were described. These reagents were readily prepared from the oxidative heptafluoroisopropylation of hydroxylamines e.g., II with AgCF(CF3)2. The substitutions on the nitrogen atom significantly affected the properties and reactivities of N-OCF(CF3)2 reagents. Accordingly, two types of N-OCF(CF3)2 reagents including I and III were used as OCF(CF3)2 anion and radical precursors, resp. This protocol enables the direct heptafluoroisopropoxylation of a range of substrates, delivering the corresponding products in moderate to excellent yields.
Angewandte Chemie, International Edition published new progress about 1289010-13-4. 1289010-13-4 belongs to pyrazoles-derivatives, auxiliary class Pyrazoles, name is 4,6-Dichloro-2-(3-methyl-1H-pyrazol-1-yl)pyrimidine, and the molecular formula is C11H14O2, SDS of cas: 1289010-13-4.
Referemce:
https://en.wikipedia.org/wiki/Pyrazole,
Pyrazoles – an overview | ScienceDirect Topics